Modeling the impact of microbial activity on redox dynamics in porous media     

Martin Thullner  Philippe Van Cappellen  Pierre Regnier 《Geochimica et cosmochimica acta》2005,69(21):5005-5019

The present study investigates the interaction between microbial growth and activity and the redox dynamics in natural porous media. The impact the transport regime has on this interaction is also addressed. Expressions for microbial growth are incorporated into a geochemical reaction network linking redox reaction rates to the activity of the microorganisms. A flexible simulation environment, the Biogeochemical Reaction Network Simulator (BRNS) is used for this purpose. Two reactive transport applications relevant to fields of contaminant hydrology and early diagenesis are simulated with the BRNS. Model results are evaluated based on a comparison with comprehensive datasets on the biodegradation of lactate in a sand column experiment and on the distribution of redox-sensitive chemical species in marine sediments of the Skagerrak, Denmark. It is shown that, despite quite different transport regimes, the geomicrobiological model performs equally well in the reproduction of measured chemical species distribution for both applications. This result emphasizes the broad applicability of the proposed approach. Our simulations support that the competitive behavior between various microbial groups is a process controlling the development of redox stratified environments. Furthermore, it is also shown that the transport regime is a key controlling factor for the degree of spatial correlation between microbial biomass distributions and redox reaction rates. Although all our simulations yield a pronounced stratification of the redox processes in the system, the biomass distribution is related to the associated reaction rates only in case of the advection controlled column experiment. In the early diagenetic application, mixing due to bioturbation is the dominant transport process for particulate matter, hence leading to fairly homogeneous distribution of bacterial biomasses which are unrelated to the spatial distribution of redox reaction rates. This homogeneous biomass distribution combined with the 1G carbon degradation model approach might explain why the steady state concentration profiles in such systems can be reproduced by diagenetic models without explicit representation of microbial growth.  相似文献   

Increasing flood risk under climate change: a pan-European assessment of the benefits of four adaptation strategies   总被引：4，自引：0，他引：4  

Lorenzo Alfieri  Luc Feyen  Giuliano Di Baldassarre 《Climatic change》2016,136(3-4):507-521

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Erratum to: Polymorphic phase transition in Superhydrous Phase B     

M. Koch-Müller  P. Dera  Y. Fei  H. Hellwig  Z. Liu  J. Van Orman  R. Wirth 《Physics and Chemistry of Minerals》2014,41(9):725-725

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A 2000‐year lipid biomarker record preserved in a stalagmite from north‐west Scotland     

Alison J. Blyth  Andy Baker  Louise E. Thomas  Peter Van Calsteren 《第四纪科学杂志》2011,26(3):326-334

Previous studies on lipid biomarkers preserved in Chinese stalagmites have indicated that ratios of low‐molecular‐weight (LMW) to high‐molecular‐weight (HMW) n‐alkanes, n‐alkan‐2‐ones, n‐alkanols and n‐alkanoic acids can be used as an index of vegetation versus microbial organic matter input to the system and, by extension, a marker of climatic changes, with increases in the proportion of LMW compounds coinciding with colder periods. Here we test whether this hypothesis is equally applicable to a different geographical region (north‐west Scotland), by examining a stalagmite record of the past 200 years, and a wider range of lipid markers. We also test the applicability of other lipid proxies in this context, including the use of n‐alkane ratios, to interpret vegetation changes, and unsaturated alkanoic acid ratios as climatic indicators. The results show that lipid proxies preserved in stalagmites, and especially those related to vegetation, are potentially extremely useful in palaeoenvironmental research. Of particular value is the use of C₂₇/C₃₁ n‐alkane ratios as a proxy for vegetation change, clearly indicating variations between herbaceous and arboreal cover. This proxy has now been successfully applied to samples from diverse environments, and can be considered sufficiently robust to be of use in analysing future stalagmite records. It will be of particular value in areas where reliable pollen records are not available, as is often the case with deeper cave deposits. However, the division between LMW and HMW aliphatic compounds is not a clear‐cut case of microbial versus plant activity, with the changes in LMW compounds relating more closely to those in their HMW analogues than in specific bacterial biomarkers. The use of unsaturated alkanoic acid ratios here gives conflicting results, with the observed variation through time depending on the isomer measured. The discrepancies between the findings of this study and previous work are likely to be due to the varying controls on the lipids (original organic matter input, and compound degradation), which in turn will be affected by whether the main climatic limiting factor on the soil is temperature or precipitation. This suggests that lipid proxies preserved in stalagmites must be interpreted with care, particularly in the case of bacterial compounds which may be derived from within the cave or from the soil. However, many of these issues can be resolved by the use of multi‐proxy studies. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Geological and geophysical studies of the Agoudal impact structure (Central High Atlas,Morocco): New evidence for crater size and age     

Houda El Kerni  Hasnaa Chennaoui Aoudjehane  David Baratoux  Mohammed Aoudjehane  Andr Charrire  Hassan Ibouh  Pierre Rochette  Yoann Quesnel  Minoru Uehara  Thomas Kenkmann  Gerwin Wulf  Michael Poelchau  Van Binh Nguyen  Maria Aboulahris  Samira Makhoukhi  Georges Aumaître  Didier Bourls  Karim Keddadouche 《Meteoritics & planetary science》2019,54(10):2483-2509

Since the discovery of shatter cones (SCs) near the village of Agoudal (Morocco, Central High Atlas Mountains) in 2013, the absence of one or several associated circular structures led to speculation about the age of the impact event, the number, and the size of the impact crater or craters. Additional constraints on the crater size, age, and erosion rates are obtained here from geological, structural, and geophysical mapping and from cosmogenic nuclide data. Our geological maps of the Agoudal impact site at the scales of 1:30,000 (6 km²) and 1:15,000 (2.25 km²) include all known occurrences of SCs in target rocks, breccias, and vertical to overturned strata. Considering that strata surrounding the impact site are subhorizontal, we argue that disturbed strata are related to the impact event. Three types of breccias have been observed. Two of them (br1‐2 and br2) could be produced by erosion–sedimentation–consolidation processes, with no evidence for impact breccias, while breccia (br1) might be impact related. The most probable center of the structure is estimated at 31°59′13.73?N, 5°30′55.14?W using the concentric deviation method applied to the orientation of strata over the disturbed area. Despite the absence of a morphological expression, the ground magnetic and electromagnetic surveys reveal anomalies spatially associated with disturbed strata and SC occurrences. The geophysical data, the structural observations, and the area of occurrence of SCs in target rocks are all consistent with an original size of 1.4–4.2 km in diameter. Cosmogenic nuclide data (³⁶Cl) constrain the local erosion rates between 220 ± 22 m Ma^?1 and 430 ± 43 m Ma^?1. These erosion rates may remove the topographic expression of such a crater and its ejecta in a time period of about 0.3–1.9 Ma. This age is older than the Agoudal iron meteorite age (105 ± 40 kyr). This new age constraint excludes the possibility of a genetic relationship between the Agoudal iron meteorite fall and the formation of the Agoudal impact site. A chronolgy chart including the Atlas orogeny, the alternation of sedimentation and erosion periods, and the meteoritic impacts is presented based on all obtained and combined data.  相似文献   

Internal erosion in granular media: direct numerical simulations and energy interpretation          下载免费PDF全文

Luc Sibille  Franck Lominé  Philippe Poullain  Yacine Sail  Didier Marot 《水文研究》2015,29(9):2149-2163

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Cracking risk of partially saturated porous media—Part I: Microporoelasticity model     

Bernhard Pichler  Luc Dormieux 《国际地质力学数值与分析法杂志》2010,34(2):135-157

Drying of deformable porous media results in their shrinkage, and it may cause cracking provided that shrinkage deformations are hindered by kinematic constraints. This is the motivation to develop a thermodynamics‐based microporoelasticity model for the assessment of cracking risk in partially saturated porous geomaterials. The study refers to 3D representative volume elements of porous media, including a two‐scale double‐porosity material with a pore network comprising (at the mesoscale) 3D mesocracks in the form of oblate spheroids, and (at the microscale) spherical micropores of different sizes. Surface tensions prevailing in all interfaces between solid, liquid, and gaseous matters are taken into account. To establish a thermodynamics‐based crack propagation criterion for a two‐scale double‐porosity material, the potential energy of the solid is derived, accounting—in particular—for mesocrack geometry changes (main original contribution) and for effective micropore pressures, which depend (due to surface tensions) on the pore radius. Differentiating the potential energy with respect to crack density parameter yields the thermodynamical driving force for crack propagation, which is shown to be governed by an effective macrostrain. It is found that drying‐related stresses in partially saturated mesocracks reduce the cracking risk. The drying‐related effective underpressures in spherical micropores, in turn, result in a tensile eigenstress of the matrix in which the mesocracks are embedded. This way, micropores increase the mesocracking risk. Model application to the assessment of cracking risk during drying of argillite is the topic of the companion paper (Part II). Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

A laboratory study of the turbulent ekman layer     

D. R. Caldwell  C. W. Van Atta  K. N. Helland 《地球物理与天体物理流体动力学》2013,107(1):125-160

Abstract

Comparing characteristics of a turbulent Ekman boundary layer in a rotating apparatus with atmospheric observations and theories, we find that the similarity relations derived by Kazanski and Monin, and others, scale both laboratory and field data quite well, especially considering that the Coriolis parameter is larger by a factor of 10⁵ in the experiment than it is in the atmosphere. Eddy viscosity models and Deardorff's numerical model predict the properties of both with varying degrees of success. High frequency spectra of velocity fluctuations scale with the Kolmogoroff length and time scales. Both magnitude and direction of the surface shear stress were measured directly, with a heated film stress gauge.  相似文献   

Multi-hazard assessment in Europe under climate change   总被引：2，自引：0，他引：2  

Giovanni Forzieri  Luc Feyen  Simone Russo  Michalis Vousdoukas  Lorenzo Alfieri  Stephen Outten  Mirco Migliavacca  Alessandra Bianchi  Rodrigo Rojas  Alba Cid 《Climatic change》2016,137(1-2):105-119

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Integrating Indoor and Outdoor Spaces for Pedestrian Navigation Guidance: A Review          下载免费PDF全文

Ann Vanclooster  Nico Van de Weghe  Philippe De Maeyer 《Transactions in GIS》2016,20(4):491-525

In light of the many improvements within 3D urban modeling and Location‐Based Services, this article provides a timely review of the state‐of‐the‐art on integrating indoor and outdoor spaces in pedestrian navigation guidance aids. With people moving seamlessly between buildings and surrounding areas, navigation guidance tools should extend from merely outdoor or indoor guidance, to provide support in the combined indoor‐outdoor context. This article first examines the challenges and complexities of integrating indoor and outdoor spaces into a single navigation system. Next, by using objective selection criteria, 36 relevant studies were withheld and further reviewed on their specific developments in data model requirements, and algorithmic and context support for integrated IO navigation systems. This review shows that the challenges of dealing with both indoor and outdoor space structures, while taking into account pedestrian's freer use of space, currently complicate the proposition of a unified IO space concept for navigation. However, there are some ongoing developments (e.g. context definitions, algorithmic extensions, increased data availability, growing awareness of pedestrians’ perception during wayfinding) that will help to bring outdoor and indoor spaces closer together in the realm of combined geospatial analysis.  相似文献